Valley density-wave and multiband superconductivity in iron-based pnictide superconductors

The key feature of the Fe-based superconductors is their quasi-two-dimensional multiband Fermi surface. By relating the problem to a negative U Hubbard model and its superconducting ground state, we show that the defining instability of such a Fermi surface is the valley density-wave VDW , a combined spin/charge densitywave at the wave vector connecting the electron and hole valleys. As the valley parameters change by doping or pressure, the fictitious superconductor experiences “Zeeman splitting,” eventually going into a nonuniform “Fulde-Ferrell-Larkin-Ovchinikov” FFLO state, an itinerant and often incommensurate VDW of the real world, characterized by the metallic conductivity from the ungapped remnants of the Fermi surface. When Zeeman splitting exceeds the “Chandrasekhar-Clogston” limit, the “FFLO” state disappears and the VDW is destabilized. Near this point, the VDW fluctuations and interband pair repulsion are essential ingredients of high-Tc superconductivity in Fe pnictides.